In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for

Fast reactions in catalyst of small pore diameter
Fast reaction in catalyst of large pore diameter
Slow reactions in catalyst of small pore diameter
Slow reactions in catalyst of large pore diameter
✅ The correct answer is option C.

At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3 = K₁.K₂
K3 = (K₁.K₂)0.5
K3(K₁+K₂)/2
K3 = (K₁.K₂)2
✅ The correct answer is option A.