A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by

keff = k + kg
keff = (k+ kg)/2
keff = (kkg)1/2
1/keff = 1/k + 1/kg
✅ The correct answer is option D.

Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation?

Langmuir
There is no dynamic equilibrium between successive layer
The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process
None of these
✅ The correct answer is option B.