A first order gaseous phase reaction is catalysed by a non-porous solid. The kinetic rate constant and the external mass transfer co-efficients are k and kg respectively. The effective rate constant (keff) is given by September 7, 2025 by Admin keff = k + kg keff = (k+ kg)/2 keff = (kkg)1/2 1/keff = 1/k + 1/kg ✅ The correct answer is option D.
With an increase in pressure in gaseous phase chemical reactions, the fractional conversion __________ when the number of moles decreases. September 7, 2025 by Admin Increases Decreases Remains unaffected Unpredictable from the data ✅ The correct answer is option A.
For multiple reactions, the flow pattern within the vessel affects the September 7, 2025 by Admin Size requirement Distribution of reaction products Both A and B Neither A nor B ✅ The correct answer is option C.
In a continuous flow stirred tank reactor, the composition of the exit stream September 7, 2025 by Admin Is same as that in the reactor Is different than that in the reactor Depends upon the flow rate of inlet stream None of these ✅ The correct answer is option A.
A chemical reaction is of zero order, when the reaction rate is (where, CA = concentration of reactant) September 7, 2025 by Admin ∝ CA ∝ 1/CA Independent of temperature None of these ✅ The correct answer is option D.
Higher free energy of activation of a chemical reaction (at a given temperature) implies September 7, 2025 by Admin Slower rate of reaction Higher rate of reaction Higher equilibrium conversion Both B and C ✅ The correct answer is option A.
Promoter is added to the catalyst to improve its September 7, 2025 by Admin Porosity Sensitivity Surface area None of these ✅ The correct answer is option B.
Catalyst is a substance, which __________ chemical reaction. September 7, 2025 by Admin Increases the speed of a Decreases the speed of a Can either increase or decrease the speed of a Alters the value of equilibrium constant in a reversible ✅ The correct answer is option A.
Brunaur, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation? September 7, 2025 by Admin Langmuir There is no dynamic equilibrium between successive layer The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process None of these ✅ The correct answer is option B.
In case of physical adsorption, the heat of adsorption is of the order of __________ kcal/kg.mole. September 7, 2025 by Admin 100 1000 10000 100000 ✅ The correct answer is option B.