For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate – rA0 is invariant with total pressure. The rate controlling step is

Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase
Surface reaction between absorbed A and absorbed B
Surface reaction between A in the gas phase and absorbed B
Desorption of C
✅ The correct answer is option D.

Pick out the wrong statement

For the same conversion, the holding time required in a batch reactor, is always equal to the space time required in a PFR
Two mixed reactors of unequal size are available for producing a specified product, formed by a homogenous second order reaction. To achieve maximum production rate, the smaller reactor should be plac
Arrehenius equation describing the effect of temperature on rate constant is given by, K = A.e-Ea/RT
The mechanism for the decomposition of CH₃CHO into CH₄ and CO in presence of I₂ is:
CH₃CHO +I₂ CH₃I + HI + CO; slow
CH₃I + HI CH₄ + I₂; fast
Then the rate of disappearance
✅ The correct answer is option D.