A batch adiabatic reactor at an initial temperature of 373°K is being used for the reaction, A → B. Assume the heat of reaction is – 1kJ/mole at 373°K and heat capacity of both A and B to be constant and equal to 50J/mole.K. The temperature rise after a conversion of 0.5 will be

5°C
10°C
20°C
100°C
✅ The correct answer is option B.

The rate expression for a heterogenous catalytic reaction is given by, – rA = K.KA PA(1 + KA.PA + Kr.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A)

E
E + ΔHA
E + ΔHA – ΔHR
ΔHA + ΔHR
✅ The correct answer is option C.