31. If n = overall order of a chemical reaction. a = initial concentration of reactant. t = time required to complete a definite fraction of the reaction. Then pick out the correct relationship. September 7, 2025 by Admin T ∝ 1/an T ∝ 1/an – 1 T ∝ 1/an + 1 T ∝ an ✅ The correct answer is option B.
32. There is no correspondence between stoichiometry and the rate equation in case of a/an __________ reaction. September 7, 2025 by Admin Elementary Multiple Autocatalytic Non-elementary ✅ The correct answer is option D.
33. For an ideal plug flow reactor, the value of Peclet number is September 7, 2025 by Admin 0 ∞ 1 10 ✅ The correct answer is option B.
34. The catalyst in a second order reversible reaction increases the rate of the forward reaction September 7, 2025 by Admin And decreases that of backward reaction And backward reaction equally Only To a greater extent than that of the backward reaction ✅ The correct answer is option B.
35. For a mixed flow reactor operating at steady state, the rate of reaction is given by September 7, 2025 by Admin FA0/V – dCsub>A/dt FA0/V + dCsub>A/dt FA0/V . Xsub>A ✅ The correct answer is option C.
36. The value of ‘n’ for a chemical reaction A → B, whose reaction rate is → CAn, will be __________ if the rate of the reaction increases by a factor of 8, when the concentration of is doubled. September 7, 2025 by Admin 0 1 2 3 ✅ The correct answer is option D.
37. Overall rate of reaction in a heterogenous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of catalyst, if it does not entail a chain mechanism. September 7, 2025 by Admin Proportional to Independent of Inversely proportional to Proportional to the square of ✅ The correct answer is option A.
38. A first order reaction requires two equal sized CSTR. The conversion is September 7, 2025 by Admin Less when they are connected in series More when they are connected in series More when they are connected in parallel Same whether they are connected in series or in parallel ✅ The correct answer is option B.
39. Reactions with high activation energy are September 7, 2025 by Admin Very temperature sensitive Temperature insensitive Always irreversible Always reversible ✅ The correct answer is option A.
40. The rate constant of a chemical reaction increases by 100 times when the temperature is increased from 400 °K to 500 °K. Assuming transition state theory is valid, the value of E/R is September 7, 2025 by Admin 8987°K 9210°K 8764°K 8621°K ✅ The correct answer is option B.