According to Raoult’s law, “The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component.” Raoult’s law is not applicable under the following assumption/condition.

No component is concentrated at the surface of the solution
The component molecules are non polar and are of almost equal size
In the formation of solution, chemical combination/molecular association between unlike molecules takes place
The attractive forces between like and unlike molecules are almost equal
✅ The correct answer is option C.

One mole of methane undergoes complete combustion in a stoichiometric amount of air. The reaction proceeds as CH₄ + 2O₂ → CO₂ + 2H₂O. Both the reactants and products are in gas phase. ΔH°298 = – 730 kJ/mole of methane. If the average specific heat of all the gases/vapour is 40 J/mole.K, the maximum temperature rise of the exhaust gases in °C would be approximately equal to

1225
1335
1525
1735
✅ The correct answer is option D.