331. For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm³ and that in vapour phase in 391.1 cm³.Fugacity of water (in kPa) at 9000 kPa will be

A. 6738.9
B. 6753.5
C. 7058.3
D. 9000
✅ The correct answer is option B.

340. A solid metallic block weighing 5 kg has an initial temperature of 500°C. 40 kg of water initially at 25°C is contained in a perfectly insulated tank. The metallic block is brought into contact with water. Both of them come to equilibrium. Specific heat of block material is 0.4 kJ.kg⁻¹. K⁻¹. Ignoring the effect of expansion and contraction and also the heat capacity to tank, the total entropy change in kJ.kg⁻¹ , K⁻¹ is

A. -1.87
B. 0
C. 1.26
D. 3.91
✅ The correct answer is option B.