281. Internal energy of an element at 1 atm and 25° C is __________ kcal/kg.mole. A. 0 B. 273 C. 25 D. None of these ✅ The correct answer is option A.
282. Third law of thermodynamics is helpful in A. Prediction of the extent of a chemical reaction B. Calculating absolute entropies of substances at different temperature C. Evaluating entropy changes of chemical reaction D. Both B and C ✅ The correct answer is option D.
283. In the equation PVn = constant, if the value of n = y = Cp/Cv, then it represents a reversible __________ process. A. Isothermal B. Adiabatic C. Isentropic D. Polytropic ✅ The correct answer is option C.
284. Cp – Cv = R is valid for __________ gases. A. Ideal B. All C. Very high pressure D. Very low temperature ✅ The correct answer is option A.
285. In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants ) A. Addition of inert gas favours the forward reaction, when Δx is positive B. Pressure has no effect on equilibrium, when Δn = 0 C. Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, – ve) or zero) D. All of the above ✅ The correct answer is option D.
286. Entropy change of mixing two liquid substances depends upon the A. Molar concentration B. Quantity (i.e. number of moles) C. Both A and B D. Neither A nor B ✅ The correct answer is option C.
287. The intensive properties are A. Molar volume, density, viscosity and boiling point B. Refractive index and surface tension C. Both A and B D. None of these ✅ The correct answer is option C.
288. Gibbs phase rule finds application, when heat transfer occurs by A. Conduction B. Convection C. Radiation D. Condensation ✅ The correct answer is option D.
289. For an exothremic reaction A. Only enthalpy change (ΔH) is negative B. Only internal energy change (ΔE) is negative C. Both ΔH and ΔE are negative D. Enthalpy change is zero ✅ The correct answer is option C.
290. Clausius – Clayperon equation is applicable to __________ equilibrium processes. A. Solid-vapor B. Solid-liquid C. Liquid-vapor D. All of the above ✅ The correct answer is option D.