11. At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by(where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) September 7, 2025 by Admin A. μ° + RT ln f B. μ°+ R lnf C. μ° + T lnf D. μ° + R/T lnf ✅ The correct answer is option A.
12. Entropy change for an irreversible process taking system and surrounding together is September 7, 2025 by Admin A. 0 B. > 0 C. < 0 D. None of these ✅ The correct answer is option B.
13. PVy = constant, holds good for an isentropic process, which is September 7, 2025 by Admin A. Reversible and isothermal B. Isothermal and irreversible C. Reversible and adiabatic D. Adiabatic and irreversible ✅ The correct answer is option C.
14. Isobaric process means a constant process. September 7, 2025 by Admin A. Temperature B. Pressure C. Volume D. Entropy ✅ The correct answer is option B.
15. Isentropic process means a constant __________ process. September 7, 2025 by Admin A. Enthalpy B. Pressure C. Entropy D. None of these ✅ The correct answer is option C.
16. The equation relating E, P, V and T which is true for all substanes under all conditions is given by (∂E/∂V)T = T.(∂P/∂T)H – P . This equation is called the September 7, 2025 by Admin A. Maxwell B. Thermodynamic equation of state C. Equation of state D. Redlich-Kwong equation of state ✅ The correct answer is option B.
17. For an isothermal reversible compression of an ideal gas September 7, 2025 by Admin A. Only ΔE = 0 B. Only ΔH =0 C. ΔE = ΔH = 0 D. DQ = dE ✅ The correct answer is option C.
18. With increase in pressure (above atmospheric pressure), the Cp of a gas September 7, 2025 by Admin A. Increases B. Decreases C. Remains unchanged D. First decreases and then increases ✅ The correct answer is option A.
19. If an ideal solution is formed by mixing two pure liquids in any proportion, then the __________ of mixing is zero. September 7, 2025 by Admin A. Enthalpy B. Volume C. Both A & B D. Neither A nor B ✅ The correct answer is option C.
20. (∂T/∂P)H is the mathematical expression for September 7, 2025 by Admin A. Specific heat at constant pressure (Cp) B. Specific heat at constant volume (Cv) C. Joule-Thompson co-efficient D. None of these ✅ The correct answer is option C.