61. For the reaction, A + B → 2B + C, rA = rB rA = -rB rA = 2rB rA = rB/2 ✅ The correct answer is option B.
62. If a solid-gas non-catalytic reaction occurs at very high temperature, the rate controlling step is the __________ diffusion. Film Ash layer Pore None of these ✅ The correct answer is option A.
63. The most suitable reactor for carrying out an auto-thermal reaction is a Batch reactor CSTR Semi-batch reactor Plug-flow reactor ✅ The correct answer is option B.
64. The catalytic activity of enzymes is due to their capacity to lower the __________ energy. Activation Potential Kinetic None of these ✅ The correct answer is option A.
65. Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is 0 1 2 3 ✅ The correct answer is option B.
66. In the converter of the contact process for the manufacture of H₂SO₄ the equilibrium conversion of SO₂ __________ (i) __________ with increase in temperature and __________ (ii) __________ with increase in the mole ratio of SO₂ to air. (i) increases (ii) decreases (i) decreases (ii) increases (i) increases (ii) increases (i) decreases (ii) decreases ✅ The correct answer is option B.
67. A stirred tank reactor compared to tubular-flow reactor provides More uniform operating conditions Permits operation at the optimum temperature for a long reaction time Higher overall selectivity for a first order consecutive reaction All of the above ✅ The correct answer is option D.
68. The rate of a homogeneous reaction is a function of Temperature and pressure only Temperature and composition only Pressure and composition only All of the above ✅ The correct answer is option D.
69. Effectiveness factor (E) of a catalyst pellet is defined as, E = (actual rate within pore of catalyst/rate if notsnowed by pore diffusion) Effectiveness factor for a first order reaction is given by (where, T = Thiele modulus) Tan hT/T Tan T/T Tan hT/tan T None of these ✅ The correct answer is option A.
70. Half-life period for a first order reaction is __________ the initial concentration of the reactant. Directly proportional to Inversely proportional to Independent of None of these ✅ The correct answer is option C.