12. The catalyst in a first order chemical reaction changes the Equilibrium constant Activation energy Heat of formation of the product Heat of reaction ✅ The correct answer is option B.
13. Which of the following will give maximum gas conversion? Fixed bed reactor Fluidised bed reactor Semi-fluidised bed reactor Plug-flow catalytic reactor ✅ The correct answer is option C.
14. In an ideal tubular-flow reactor There is no mixing in longitudinal direction Mixing takes place in radial direction There is a uniform velocity across the radius All of the above ✅ The correct answer is option D.
15. If ‘n’ is the order of reaction, then unit of rate constant is 1/(time)(concentration)n – 1 (time)-1 (concentration)n – 1 (time)n – 1 (concentration) None of these ✅ The correct answer is option A.
16. Study of chemical kinetics is the easiest in the case of __________ reactions. Irreversible Reversible Surface Side ✅ The correct answer is option A.
17. An isothermal aqueous phase reversible reaction, P ⇋ R, is to be carried out in a mixed flow reactor. The reaction rate in k.mole/m³ .h is given by, r = 0.5CP – 0.125CR. A stream containing only P enters the 0.8 1.33 1.6 2.67 ✅ The correct answer is option C.
18. If the time required for half change is inversely proportional to the square of initial concentration and the velocity depends on the units in which the concentration term is expressed, then the order of reaction is 1 2 3 0 ✅ The correct answer is option C.
19. In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for Fast reactions in catalyst of small pore diameter Fast reaction in catalyst of large pore diameter Slow reactions in catalyst of small pore diameter Slow reactions in catalyst of large pore diameter ✅ The correct answer is option C.
20. At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as: K3 = K₁.K₂ K3 = (K₁.K₂)0.5 K3(K₁+K₂)/2 K3 = (K₁.K₂)2 ✅ The correct answer is option A.